The Armspach Group

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BINOL-derived phosphoramidites in asymmetric hydrogenation: can the presence of a functionality in the amino group influence the catalytic outcome?
L. Eberhardt, D. Armspach, J. Harrowfield, D. Matt,
Chem. Soc. Rev. 2008, 37, 839-864.

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Synthesis and properties of TRANSDIP, a rigid chelator built upon a cyclodextrin cavity. Is TRANSDIP an authentic trans-spanning ligand?
L. Poorters, D. Armspach, D. Matt, L. Toupet, S. Choua, P. Turek,
Chem. Eur. J. 2007, 13, 9448-9461.

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Efficient asymmetric hydrogenation of olefins with hydrazine-derived diphosphoramidites
L. Eberhardt, D. Armspach, D. Matt, B. Oswald, L. Toupet,
Org. Biomol. Chem. 2007, 5, 3340–3346.

Chiral selectors for enantioresolution and quantitation of the antidepressant drug uoxetine in pharmaceutical formulations by
19F NMR spectroscopic method
M. Shamsipur, L. S. Dastjerdi, S. Haghgoo, D. Armspach, D. Matt, H. Y. Aboul-Enein
Anal. Chim. Acta 2007, 601, 130-138.

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Efficient, rhodium-catalyzed hydrogena tion of α-dehydroamino acid esters with chiral monodentate aminophosphanes bearing two binaphthyl groups
L. Eberhardt, D. Armspach, D. Matt, L. Toupet, B. Oswald,
Eur. J. Org. Chem. 2007, 5395-5403.

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α-TEPHOS: A cyclodextrin-derived tetraphosphine for multiple metal binding
L. Poorters, D. Armspach, D. Matt, L. Toupet,
Dalton Trans. 2007, 3195-3202.

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23. Synthesis of chiral, monodentate aminophosphine and phosphoramidite ligands derived from amino acid esters. Application in the Rh-catalysed asymmetric olefin hydrogenation
L. Eberhardt, D. Armspach, D. Matt, L. Toupet, B. Oswald,
Eur. J. Inorg. Chem. 2007, 4153-4161.

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A metallocavitand functioning as a container for anions. Formation of non-covalent, linear assemblies mediated by a cyclodextrin-entrapped NO
3 anion
L. Poorters, D. Armspach, D. Matt, L. Toupet,
Angew. Chem. Int. Ed. 2007, 46, 2663-2665.

Cyclodextrin-based thiacavitands as building blocks for the construction of metallo-nanotubes
D. Armspach, L. Poorters, D. Matt, B. Benmerad, P. Jones, I. Dix, L. Toupet,
J. Incl. Phenom. Macrocycl. Chem, 2007, 57, 243-250.

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Sulfur-capped cyclodextrins: a new class of cavitands with extroverted as well as introverted donor functionalities
B. Benmerad, P. Clair, D. Armspach, D Matt, F. Balegroune, L. Toupet,
Chem. Commun. 2006, 2678-2680.